RT Journal Article
T1 Metastability in drowning-out crystallisation: precipitation ofhighly soluble sulphates
A1 Pina Martínez, Carlos Manuel
A1 Fernández Díaz, Lurdes
A1 Prieto Rubio, Manuel
A1 Veintemillas Verdagher, Sabino
AB In this paper we derive equations for evaluating the supersaturation, b, and the supersaturation rate, Rb, for the drowning-out crystallisation under isothermal conditions and assuming a constant rate of the addition of the co-solvent. Such equations are applied to the drowning-out crystallisation of single and double sulphates in theM2SO4±LiSO4±H2O (M=Na, Rb) ternary systems. A linear relationship between lnRb and ln bmax, similar to that reported for the crystallisation by cooling, evaporation and chemical reaction, has been found.
PB Elsevier Science B.V.
SN 0022-0248
YR 2001
FD 2001
LK https://hdl.handle.net/20.500.14352/57123
UL https://hdl.handle.net/20.500.14352/57123
LA eng
DS Docta Complutense
RD 30 abr 2024