RT Journal Article
T1 BCl3‑Activated Synthesis of COO-BODIPY Laser Dyes: General Scope and High Yields under Mild Conditions
A1 Ray Leiva, César
A1 Schad, Christopher
A1 Moreno Jiménez, Florencio
A1 Maroto, Beatriz Lora
A1 Bañuelos Prieto, Jorge
A1 Arbeloa, Teresa
A1 García Moreno, Inmaculada
A1 Villafuerte, Cassie
A1 Muller, Gilles
A1 Moya Cerero, Santiago de la
AB A general and straightforward method for the synthesis of COO-BODIPYs from F-BODIPYs and carboxylic acids is established. The method is based on the use of boron trichloride to activate the involved substitution of fluorine, which leads to high yields through rapid reactions under soft conditions. This mild method opens the way to unprecedented laser dyes with outstanding efficiencies and photostabilities, which are difficult to obtain by the current methods.
PB ACS
SN 0022-3263 (Print) 1520-6904(Online)
YR 2020
FD 2020-03-06
LK https://hdl.handle.net/20.500.14352/8663
UL https://hdl.handle.net/20.500.14352/8663
LA eng
NO Ray C, Schad C, Moreno F, Maroto BL, Bañuelos J, Arbeloa T, García-Moreno I, Villafuerte C, Muller G, De La Moya S. BCl3 -Activated Synthesis of COO-BODIPY Laser Dyes: General Scope and High Yields under Mild Conditions. J Org Chem 2020; 85: 4594–4601. [DOI: 10.1021/acs.joc.9b03059]
NO Ministerio de Ciencia e Innovación (España)
NO Gobierno Vasco
DS Docta Complutense
RD 10 abr 2025