%0 Journal Article
%A San Martín, Daniel
%A Martínez Del Campo, Teresa
%A Gamarra, L.
%A Cerrón, E.
%A Cembellín Santos, Sara
%A Yanai, H.
%A Almendros, P.
%T Indium-mediated preparation of bis(α-hydroxyallenes) or α,α´-dihydroxyallenynes and further gold-catalyzed cyclizations
%D 2024
%U https://hdl.handle.net/20.500.14352/122888
%X We present the regio- and diastereoselective Barbier-type allenylation reaction of glyoxals mediated by indium to furnish highly valuable syn-bis(α-hydroxyallenes) and syn-α,α′-dihydroxyallenynes. The gold-catalyzed controlled cyclization of these unsaturated diols enables the divergent preparation of three types of oxacycles.
%~