RT Journal Article T1 Towards Lead-Free Piezoceramics: Facing a Synthesis Challenge A1 Villafuerte-Castrejón, María A1 Morán, Emilio A1 Reyes-Montero, Armando A1 Vivar-Ocampo, Rodrigo A1 Peña-Jiménez, Jesús-Alejandro A1 Rea-López, Salvador-Oliver A1 Pardo, Lorena AB The search for electroceramic materials with enhanced ferro-pyro-piezoelectric properties and revealing the perovskite type structure has been the objective of a significant number of manuscripts reported in the literature. This has been usually carried out by proposing the synthesis and processing of new compounds and solid solution series. In this work, several methods to obtain ferro-pyro-piezoelectric families of materials featuring the well-known ABO3 perovskite structure (or related) such as BaTiO3, Ba1–xCaxTi1–yZryO3, (Bi0.5Na0.5)TiO3, (K0.5Na0.5)NbO3 and their solid solutions with different cations either in the A or B positions, are presented. For this kind of materials, the challenge for obtaining a single phase compound with a specific grain size and morphology and, most importantly, with the adequate stoichiometry, will also be discussed. The results reviewed herein will be discussed in terms of the tendency of working with softer conditions, i.e., lower temperature and shorter reaction times, also referred to as soft-chemistry. PB MDPI SN 1996-1944 YR 2016 FD 2016-01-02 LK https://hdl.handle.net/20.500.14352/23871 UL https://hdl.handle.net/20.500.14352/23871 LA eng NO Ministerio de Economía y Competitividad (MINECO) NO Comunidad de Madrid NO CSIC NO Universidad Nacional Autónoma de México/DGAPA DS Docta Complutense RD 19 abr 2025