RT Journal Article
T1 Microtopography of the barite (001) face during growth:AFM observations and PBC theory
A1 Pina Martínez, Carlos Manuel
A1 Bosbach, Dirk
A1 Prieto Rubio, Manuel
A1 Putnis, Andrew
AB Under moderate supersaturation conditions, crystal growth on the barite (0 0 1) surface takes place by the developmentof two-dimensional nucleation simultaneously with the advancement of molecular-height cleavage steps on thesurface. The most frequent growth steps have a height of a half-unit cell, as has been predicted by periodic bond chain(PBC) theory, and they are parallel to the S1 2 0T PBC directions. Along opposite directions the velocity of S1 2 0Tgrowth steps is strongly anisotropic. Moreover, the directions of fast growth alternate for successive elementary growthlayers. The anisotropy of the growth rates can be explained by taking into account the crystallographic features andorientation of the complete PBC within each (0 0 2) elementary growth slice. On the other hand, the alternation of the fastgrowth direction for S1 2 0T steps in successive d002 growth layers is related to the existence of a 21 screw axisperpendicular to the (0 0 1) surface. Two-dimensional nucleation on the barite (0 0 1) surface is characterized by thedevelopment of islands with a circular sector shape and half-unit cell in height. The two-dimensional islands nucleated onthe initial surface show the same orientation. As growth proceeds, islands coalesce and a homogeneous layer witha thickness of 3.5 A is formed. Nucleation on this new surface produces islands oriented in the opposite sense to those inthe previous layer. Goniometric measurements and X-ray di¤raction experiments conÞrm that the straight edges of theislands are parallel to the [1 2 0] and [1 2 0] crystallographically equivalent directions. The third side of each island iscurved, rough and tangent to [010]. Both the morphology and development of two-dimensional nuclei on the barite(001) face clearly indicate that the growth process is structurally controlled. The asymmetry of [120], [120] and[010] PBCs and their crystallographic features can be considered as responsible for the geometry and spread of thecircular sector islands formed on each elementary (002) growth layer.
PB Elsevier Science B.V.
SN 0022-0248
YR 1998
FD 1998
LK https://hdl.handle.net/20.500.14352/57124
UL https://hdl.handle.net/20.500.14352/57124
LA eng
DS Docta Complutense
RD 15 dic 2025