TY - JOUR AU - Krämer, F. AU - Crabbe, Michelle H. AU - Fernández López, Israel AU - Mulvey, Robert E. PY - 2025 DO - 10.1002/anie.202516376 UR - https://hdl.handle.net/20.500.14352/131560 T2 - Angewandte Chemie International Edition AB - We present a study of the ability of our recently reported well-defined crown ether-coordinated alkali metal phosphides 1AM to catalyze hydrophosphination (HP) of alkynes and alkenes. In a comparative study including reaction monitoring by 1H NMR... LA - eng M2 - e202516376 PB - Wiley KW - Alkali metals KW - Alkenes KW - Alkynes KW - Catalysis KW - Hydrophosphination TI - Heavyweight Champion: Caesium Diorganophosphides Outperform Lighter Congeners in the Catalytic Hydrophosphination of Alkenes and Alkynes TY - journal article VL - 64 ER -