RT Journal Article
T1 Novel 3-ethoxysalicylaldehyde lanthanide complexes obtained by decomposition of salen-type ligands
A1 Mediavilla, Paula
A1 Ribeiro González, Antonio
A1 Gutiérrez Alonso, Ángel
A1 Herrero Domínguez, Santiago
A1 Torralba Martínez, María Del Carmen
AB Three new asymmetrically coordinated lanthanide derivatives based on the bicompartmental salen-type ligands N,N′-bis(3-ethoxysalicylidene)propylene-1,3-diamine (H2EtOsalpr) and 3-ethoxysalicylaldehyde (HEtvain) have been synthesized and structurally and photophysically characterized. All the compounds show dimeric structures of the general formula [Ln(H2EtOsalpr)(NO3)2(Etvain)]2 (Ln = Nd, Eu, Dy), with each salen-type ligand bridging two lanthanide ions. The Etvain ligand comes from the H2EtOsalpr decomposition being coordinated to the corresponding lanthanide. The Nd(III) derivative shows fluorescence emission in the NIR region, but for the Eu(III) and Dy(III) compounds, only a broad band, attributed to the ligand emission, was observed.
PB MDPI
YR 2025
FD 2025-03-19
LK https://hdl.handle.net/20.500.14352/129451
UL https://hdl.handle.net/20.500.14352/129451
LA eng
NO Mediavilla, Paula, et al. «Novel 3-Ethoxysalicylaldehyde Lanthanide Complexes Obtained by Decomposition of Salen-Type Ligands». Inorganics, vol. 13, n.o 3, marzo de 2025, p. 93. DOI.org (Crossref), https://doi.org/10.3390/inorganics13030093.
NO Complutense University of Madrid
NO Community of Madrid
NO European Union
NO Ministry of Science, Innovation and Universities
DS Docta Complutense
RD 21 abr 2026