RT Journal Article T1 Electrical properties of rapid thermally annealed SiNx : H/Si structures characterized by capacitance-voltage and surface photovoltage spectroscopy A1 Mártil de la Plaza, Ignacio A1 González Díaz, Germán A1 Prado Millán, Álvaro del A1 San Andrés Serrano, Enrique AB A comparative investigation of the characteristics of the SiNx:H/Si interface has been undertaken by capacitance-voltage measurements and surface photovoltage spectroscopy. By each of these techniques, we have determined the distribution of the interface trap density within the silicon bandgap. The samples were grown by the electron-cyclotron resonance plasma method starting from SiH4 and N-2 as precursor gases whose flow ratio was varied to produce films of three different compositions: silicon rich, near stoichiometric and nitrogen rich. Post-deposition rapid thermal annealing treatments were applied to observe the evolution of interface properties with the annealing temperature in the range from 300 to 1050 degreesC. For thin dielectrics, the interface state density has a U-shaped distribution dominated by hand-tail states. The minimum of this distribution decreases significantly and shifts to midgap for moderate annealing temperatures. For higher annealing temperatures, the trend is reversed. In the silicon-rich films, the percolation of rigidity caused by the chains of Si-Si bonds impedes the initial decrease of the defect density. For thicker films, the strain of the: SiNx:H film produces a higher density of defects that results in increased levels of leakage currents and poorer electrical characteristics. PB Iop Publishing Ltd SN 0268-1242 YR 2001 FD 2001-07 LK https://hdl.handle.net/20.500.14352/59108 UL https://hdl.handle.net/20.500.14352/59108 LA eng NO [1] The SIA Roadmap for Semiconductor Technology, 1997 (Santa Clara, CA).[2] Yang, H.Y., Niimi, H. and Lucovsky, G., 1998, J. Appl. Phys., 83, 2327.[3] Niimi, H. and Lucovsky, G., 1999, J. Vac. Sci. Technol. B, 17, 2610.[4] Wu, Y., Lee, Y.M. and Lucovsky, G., 2000, IEEE Electron Device Lett., 21, 116.[5] Ma, Y., Yasuda, T. and Lucovsky, G., 1994, Appl. Phys. Lett., 64, 2226.[6] García, S., Mártil, I., González-Díaz, G., Castán, E., Dueñas, S. and Fernández, M., 1998, J. Appl. Phys., 83, 332.[7] Hugon, M.C., Delmotte, F., Agius, B. and Courant, J.L., 1997, J. Vac. Sci. Technol. A, 15, 3143.[8] Mohammad, S.N., Tao, M., Park, D.G., Botchkarev, A.E., Li, D. and Morkoc, H., 1996, Phil. Mag. B, 73, 817.[9] Park, D.G., Reed, J.C. and Morkoc, H., 1997, Appl. Phys. Lett., 71, 1210.[10] Landheer, D., Rajesh, K., Masson, D., Hulse, J.E., Sproule, G.I. and Quance, T., 1998, J. Vac. Sci. Technol. A, 16, 2931.[11] Lu, Z., He, S.S., Ma, Y. and Lucovsky, G., 1995, J. Non-Cryst. Solids, 187, 340.[12] Lu, Z., Santos-Filho, P., Stevens, G., Williams, M.J. and Lucovsky, G., 1995, J. Vac. Sci. Technol. A, 13, 607.[13] Park. D,G., et al., 1996, J. Vac. Sci. Technol. B, 14, 2674.[14] Martínez, F.L., del Prado, À., Bravo, D., López, F., Mártil, I. and González-Díaz, G., 1999, J. Vac. Sci. Technol. A, 17, 1280.[15] Martínez, F.L., Mártil, I., González-Díaz, G., Selle, B. and Sieber, I., 1998, J. Non-Cryst. Solids, 227–230, 523.[16] Martínez, F.L., del Prado, Á., Mártil, I., González-Díaz, G., Selle, B. and Sieber, I., 1999, J. Appl. Phys., 86, 2055.[17] Bohne, W., Fuhs, W., Röhrich, J., Selle, B., González-Díaz, G., Mártil, I., Martínez, F.L. and del Prado, Á., 2000, Surf. Interface Anal., 30, 534.[18] Martínez, F.L., del Prado, Á., Mártil, I., Bravo, D. and López, F.J., 2000, J. Appl. Phys., 88, 2149.[19] Heilig, K., Flietner, H. and Reineke, J., 1979, J. Phys. D: Appl. Phys., 12, 927.[20] Shimizu, H. and Munakata, C., 1994, Appl. Phys. Lett., 64, 3598.[21] Kamieniecki, E., 1985, J. Appl. Phys., 57, 2840.[22] Marsi, M., et al., 2000, Phys. Rev. B, 61, R5070.[23] Heilig, K., Kolbig, E. and Reineke, J., 1989, Phys. Status Solidi A, 114, 579.[24] Burstein, L., Bregman, J. and Shapira, Y., 1991, J. Appl. Phys., 69, 2312.[25] Yan, Y., 1997, Appl. Phys. Lett., 71, 407.[26] García, S., Martín, J.M., Fernández, M., Mártil, I. and González-Díaz, G., 1996, Phil. Mag. B, 73, 487.[27] Lam, Y.W., 1971, J. Phys. D: Appl. Phys., 4, 1370.[28] Nicollian, E.H. and Brews, J.R., 1982, MOS (Metal Oxide Semiconductor) Physics and Technology (New York: Wiley). NO © 2001 IOP Publishing Ltd. We wish to thank the financial support of the Spanish National Office for Science and Technology under grant no TIC98-0740 and the technical assistance of the ion implantation center ‘CAI-Implantación Iónica’ of the University of Madrid. NO Spanish National Office for Science and Technology DS Docta Complutense RD 3 may 2024