RT Journal Article
T1 Cycloadditions and cyclization reactions via post-synthetic modification and/or one-pot methodologies for the stabilization of mine-based covalent organic frameworks
A1 Gala Sánchez, Elena
A1 Ramos, M. Mar
A1 Segura Castedo, José Luis
AB Interest in covalent organic frameworks as high-value materials has grown steadily since their development in the 2000s. However, the great advantage that allows us to obtain these crystalline materials—the reversibility of the bonds that form the network—supposes a drawback in terms of thermal and chemical stability. Among the different strategies employed for the stabilization of imine-based Covalent Organic Frameworks (COFs), cycloaddition and other related cyclization reactions are especially significant to obtain highly stable networks with extended π-delocalization and new functionalities, expanding even further the potential application of these materials. Therefore, this entry gathered the most recent research strategies for obtaining stable COFs by means of cyclization reactions, including the Povarov reaction and intramolecular oxidative cyclization reactions as well as some other recent innovative approaches.
PB MDPI
YR 2023
FD 2023-06-25
LK https://hdl.handle.net/20.500.14352/104060
UL https://hdl.handle.net/20.500.14352/104060
LA eng
NO Gala, E.; Ramos, M.M.; Segura, J.L. Cycloadditions and Cyclization Reactions via Post-Synthetic Modification and/or One-Pot Methodologies for the Stabilization of Imine-Based Covalent Organic Frameworks. Encyclopedia 2023, 3, 795-807. https://doi.org/10.3390/encyclopedia3030057
NO 2023 Descuentos MDPI
NO Ministerio de Ciencia e Innovación (España)
NO Universidad Complutense de Madrid
DS Docta Complutense
RD 10 jun 2025