RT Journal Article T1 Gahnite, chrysoberyl and beryl co-occurrence as accessory mineralsin a highly evolved peraluminous pluton: The Belvís de Monroyleucogranite (Cáceres, Spain) A1 Merino Martínez, Enrique A1 Villaseca González, Carlos A1 Orejana García, David A1 Jeffries, Teresa E. AB Gahnite (ZnAl2O4), chrysoberyl (BeAl2O4) and beryl (Be3Al2Si6O18) have been found as accessory minerals in the external, highly fractionated, leucogranitic unit within the Hercynian reversely zoned Belvís de Monroy pluton (westernmost part of the Montes de Toledo batholith, Cáceres, Spain). The highly felsic (SiO2 > 72 wt.%) and peraluminous (ACNK > 1.2) character of this leucogranite, together with the high content of some incompatible elements (F, Li, B, and P), seems to be a primary consequence of fractional crystallization in a magmatic closedsystem. The high Be contents and Zn/FeTotal ratio (>0.01) are relevant factors which have favoured the precipitation of these minerals. Moreover, the Si, Al, P, B, and F activities might be high, favouring the magmatic crystallization of such exotic mineral phases together with Be-rich cordierite, F-rich micas, sillimanite and Alrich phosphates. In fact, the interplay between the silica and alumina activities likely controls the stabilization and the preferential crystallization of gahnite + chrysoberyl or beryl + chrysoberyl assemblages in mm-sized microdomains. The P–T crystallization conditions are constrained by the muscovite and sillimanite stability fields and the minimum granite Al2O3-saturated solidus, and have been estimated at temperatures between 670 and 700 °C, and pressures between 1 and 2 kbar. PB Elsevier Science B.V., Amsterdam SN 0024-4937 YR 2013 FD 2013 LK https://hdl.handle.net/20.500.14352/43380 UL https://hdl.handle.net/20.500.14352/43380 LA eng NO Ministerio de Economía y Competitividad de España DS Docta Complutense RD 7 abr 2025