RT Journal Article
T1 Metal-Atom Impact on the Self-Assembly of Cup-and-Ball Metalloporphyrin–Fullerene Conjugates
A1 Moreira, Luis
A1 Calbo, Joaquín
A1 Illescas, Beatriz M.
A1 Aragó, Juan
A1 Nierengarten, Iwona
A1 Delavaux-Nicot, Béatrice
A1 Ortí, Enrique
A1 Martín, Nazario
A1 Nierengarten, Jean-Françoise
AB A fullerene-ammonium derivative has been combined with different metalloporphyrin-crown ether receptors to generate very stable supermolecules. The combination of fullerene-porphyrin and ammonium-crown ether interactions leads to a strong chelate effect as evidenced by a high effective molarity (3.16 M). The different parameters influencing the stability of the supramolecular ensembles,in particular the nature of the metal in the porphyrin moiety, have been rationalized with the help of theoretical calculations thus providing new insights into fullerene-porphyrin interactions.
PB Wiley-Vch
SN 1433-7851 (Int.Ed. print) , 1521-3773 (Int.Ed. internet)
YR 2015
FD 2015
LK https://hdl.handle.net/20.500.14352/35068
UL https://hdl.handle.net/20.500.14352/35068
LA eng
NO Comunidad de Madrid
NO Ministerio de Economía y Competitividad (MINECO)
NO European Research Council
NO Generalitat Valenciana
NO European FEDER
DS Docta Complutense
RD 7 abr 2025