%0 Journal Article
%A Garcı́a Martı́nez, Antonio
%A Teso Vilar, Enrique
%A Moreno Jiménez, Florencio
%A Álvarez Garcı́a, Ana Mª
%T A short and convenient procedure for the stereoselective synthesis of 2-hydroxy-1-norbornanesulfonamides
%D 2004
%@ 0957-4166
%U https://hdl.handle.net/20.500.14352/52835
%X A short and convenient procedure for the stereoselective synthesis of novel optically active 2-hydroxy-1-norbornanesulfonamides starting from commercially available natural camphor and fenchone is reported. The synthetic route involves a nucleophilic substitution at the sulfenyl sulfur atom of 2-methylene-1-norbornylthiotriflates followed by oxidation of the intermediate sulfenamides and highly diastereoselective reduction of the carbonyl group of the parent 2-oxo-1-norbornanesulfonamides.
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