RT Journal Article T1 Photoluminescence studies of heat-treated GaP-s samples A1 Monteiro, T. A1 Pereira, E. A1 Domínguez-Adame Acosta, Francisco A1 Piqueras De Noriega, Francisco Javier AB Time resolved photoluminescence (TRPL) of untreated and heat-treated n-type GaP:S samples has been investigated and compared with data from cathodoluminescence in a scanning electron microscope (CL-SEM). Special attention is given to broad emission bands in the region of 1.8 to 1.6 eV. TRPL shows that dependent on temperature different optical centers are responsible for the luminescence. While the low temperature emission presents a donor-acceptor (D-A) pair behavior above 70 K an excitonic emission dominates with an exponential decay (of the order of seconds at 70 K) in the whole temperature region where it is measured. The temperature behavior of the decay and intensity of these bands leads to the understanding of the processes involved in the luminescence. From the data the distribution of the defects and the levels involved in the emission are discussed. The influence of the annealing in the rearrangement of the defects is analyzed. PB Electrochemical Soc Inc SN 0013-4651 YR 1993 FD 1993-12 LK https://hdl.handle.net/20.500.14352/59276 UL https://hdl.handle.net/20.500.14352/59276 LA eng NO © 1993 ECS - The Electrochemical Society.Financial support from JNICT and DGICYT (Project PB 90-1017) is gratefully acknowledged. One of us (T: M.) thanks JNCT for a maintenance grant (BD/88/90-RM). This work was partially supported by the Portuguese-Spanish joint program . Mr. J. Januario helped in the experiments. NO DGICYT NO JNICT DS Docta Complutense RD 6 abr 2025