RT Journal Article
T1 Post-Synthetic Engineering of Covalent Organic Frameworks with Thiophene and Naphthalimide Units for Enhanced Oxygen Reduction Electrocatalysis
A1 Gala, Elena
A1 Martínez Periñán, Emiliano
A1 Martínez Fernández, Marcos
A1 Gordo Lozano, Marta
A1 Martínez, José Ignacio
A1 Segura Castedo, José Luis
AB The development of efficient metal-free electrocatalysts for the oxygen reduction reaction (ORR) is essential for advancing sustainable energy technologies. In this work, we report the post-synthetic functionalization of covalent organic frameworks (COFs) with donor–acceptor (D–A) motifs incorporating thiophene and naphthalimide derivatives, yielding two novel materials. These COFs were synthesized via CuAAC click chemistry and thoroughly characterized. Electrochemical analyses revealed enhanced ORR activity in both materials, with one COF exhibiting near-ideal four-electron selectivity and remarkable stability. Density functional theory (DFT) calculations corroborated the experimental results, demonstrating that the electronic structure of COFs facilitates efficient O–O bond cleavage and electron transfer. These findings underscore the potential of rationally designed D–A COFs as high-performance, metal-free ORR electrocatalysts, contributing to the development of next-generation sustainable energy conversion technologies.
PB RSC
YR 2025
FD 2025-10-28
LK https://hdl.handle.net/20.500.14352/125552
UL https://hdl.handle.net/20.500.14352/125552
LA eng
NO Gala, Elena, et al. «Post-Synthetic Engineering of Covalent Organic Frameworks with Thiophene and Naphthalimide Units for Enhanced Oxygen Reduction Electrocatalysis». Materials Chemistry Frontiers, 2025, p. 10.1039.D5QM00655D. DOI.org (Crossref), https://doi.org/10.1039/D5QM00655D.
NO Ministerio de Ciencia, Innovación y Universidades
NO Comunidad deMadrid
DS Docta Complutense
RD 6 abr 2026