RT Journal Article
T1 Tetrakis{[(p-dodecacarboranyl)methyl]stilbenyl}ethylene:A Luminescent Tetraphenylethylene (TPE) Core System
A1 Cabrera González, Justo Enrique
AB The synthesis and spectroscopic characterization of the first set of tetrakis{[(p-dodecacarboranyl)methyl]stilbenyl}ethylenes (TDSE), substituted either with a methyl or a phenyl group in the 2-position (Ccluster) of the ortho-carborane, are described. The complex absorption properties are elucidated by TD-DFT calculations, stressing the importance of through-bond conjugation. Enhanced conjugation and restriction of the conformational space are identified as the main factors for boosted luminescence properties in solution, compared with the tetraphenylethylene (TPE) core, effectively reducing internal conversion (IC). IC is further reduced when aggregate suspensions of our compounds are formed in water, providing highly luminescent materials of quasi-isolated (very weakly interacting) emitters.
PB Wiley-VCH
SN 1434-1948
YR 2017
FD 2017-10-18
LK https://hdl.handle.net/20.500.14352/98081
UL https://hdl.handle.net/20.500.14352/98081
LA eng
NO Ministerio de Economía y Competitividad(España)
NO Generalitat de Catalunya
NO Universidad Nacional Autónoma de México
DS Docta Complutense
RD 31 ago 2024