RT Journal Article
T1 Palladium-catalyzed cocyclotrimerization of arynes with a pyramidalized alkene
A1 Alonso Gómez, José Miguel
A1 Quiroga, Sabela
A1 Codony, Sandra
A1 Turcu, Andreea
A1 Barniol-Xicota, Marta
A1 Pérez, Dolores
A1 Guitián, Enrique
A1 Vázquez, Santiago
A1 Peña, Diego
AB A pyramidalized alkene and diverse arynes are generated in the presence of a Pd-catalyst to afford [2+2+2] cocycloaddition products.The metal-catalyzed 2+2+2] cocycloaddition of arynes with pyramidalized alkenes is presented. The generation of a highly reactive pyramidalized alkene in the presence of a large excess of in situ-produced arynes led to the corresponding cocyclotrimerization (1 : 2)-adducts in good yields, establishing the first example of a palladium-based reaction of a pyramidalized alkene.
PB Royal Society of Chemistry
SN 1359-7345
YR 2018
FD 2018
LK https://hdl.handle.net/20.500.14352/92578
UL https://hdl.handle.net/20.500.14352/92578
LA eng
NO Alonso, J. M.; Quiroga, S.; Codony, S.; Turcu, A. L.; Barniol-Xicota, M.; Pérez, D.; Guitián, E.; Vázquez, S.; Peña, D. Palladium-catalyzed cocyclotrimerization of arynes with a pyramidalized alkene. Chem. Commun. 2018, 54, 5996-5999 DOI:10.1039/C8CC03188F.
NO Xunta de Galicia
NO European Commission
NO Ministerio de Ciencia e Innovación (España)
DS Docta Complutense
RD 6 oct 2024