RT Journal Article
T1 C-Branched chiral (racemic) macrocyclic amino acids: Structure of their Ni(ii), Zn(ii) and Cu(ii) complexes
A1 Pellico, D
A1 Gómez Gallego, María Del Mar
A1 Escudero, Rosa
A1 Ramírez López, P.
A1 Oliván, M.
A1 Sierra, M.A.
AB A new procedure for the synthesis of macrocyclic embedded bis-α-amino acids and their use as cation-ligands is described. These compounds are able to form stable Cu(ii), Zn(ii) and Ni(ii) complexes as long as they have a flexible tether between the two nitrogen atoms. For a given macrocycle, the X-ray diffraction studies revealed diastereomerically pure complexes having different geometries depending on the metal ion.
PB The Royal Society of Chemistry.
YR 2011
FD 2011
LK https://hdl.handle.net/20.500.14352/117541
UL https://hdl.handle.net/20.500.14352/117541
LA eng
NO Pellico, D., Gómez-Gallego, M., Escudero, R., Ramírez-López, P., Oliván, M., & Sierra, M. A. (2011). C-Branched chiral (racemic) macrocyclic amino acids: Structure of their Ni(ii), Zn(ii) and Cu(ii) complexes. Dalton Transactions, 40(36), 9145-9153. https://doi.org/10.1039/C1DT10539F
NO Comunidad de Madrid
NO Ministerio de Ciencia, Innovación y Universidades
DS Docta Complutense
RD 10 abr 2025