RT Journal Article
T1 Hierarchy of asymmetry in chiral supramolecular polymers: toward functional, helical supramolecular structures
A1 Greciano Raiskila, Elisa Emilia
A1 Valera González, Jorge Santos
A1 Gómez Aspe, Rafael
A1 Sánchez Martín, Luis
AB The formation of helical structures through the supramolecular polymerization of a variety of self-assembling units is reviewed. These scaffolds are usually obtained by efficient transfer or amplification of chirality phenomena, in which the starting self-assembling molecules possess different elements of asymmetry, such as point or axial chirality. Relevant examples of helical supramolecular structures investigated under thermodynamic control are reviewed, and the helical outcome of remarkable examples of chiral entities obtained through kinetic control are also highlighted. Finally, selected examples of flexible macroscopic chirality and catalysis are described to illustrate the applicability of helical aggregates.
PB Wiley-VCH
YR 2019
FD 2019
LK https://hdl.handle.net/20.500.14352/105945
UL https://hdl.handle.net/20.500.14352/105945
LA eng
NO Chem. Eur. J. 2019, 25, 5848 – 5864
NO MCIU of Spain
DS Docta Complutense
RD 29 jun 2025