RT Journal Article
T1 Gas–Solid Heterogeneous Postsynthetic Modification of Imine-Based Covalent Organic Frameworks
A1 Segura Castedo, José Luis
A1 Martín Illán, Jesús A.
A1 Royuela, Sergio
A1 Ramos, M. Mar
A1 Zamora, Félix
AB The copper-catalyzed azide–alkyne cycloaddition (CuAAC) click reaction is among the most extensively used strategies for the post-polymerization modification of COFs. This work shows a new procedure for the postsynthetic functionalization of imine-based COFs by using a heterogeneous solid–gas reaction between alkyne-functionalized COFs and azides in the absence of a copper catalyst. This new alternative represents a step forward towards a greener postsynthetic modification of COFs opening a high potential for the development of new applications.
PB Chemistry Europe
YR 2020
FD 2020-02-14
LK https://hdl.handle.net/20.500.14352/129756
UL https://hdl.handle.net/20.500.14352/129756
LA eng
NO Martín-Illán, Jesús A., et al. «Gas–Solid Heterogeneous Postsynthetic Modification of Imine-Based Covalent Organic Frameworks». Chemistry - A European Journal, vol. 26, no. 29, 2020, pp. 6495-6498. https://doi.org/10.1002/chem.202000224
NO Ministerio de Economía y Competitividad (España)
DS Docta Complutense
RD 26 feb 2026