RT Journal Article
T1 1,2-Stereochemical induction in the Pd(II)-Catalyzed conjugate addition of boronic acids
A1 Roscales García, Silvia
A1 Sánchez, Francisco
A1 García Csaky, Aurelio
AB Pd(II) catalysis has been used for substrate-controlled 1,2-stereoselective conjugate addition of boronic acids to enantiopure α,β-acyclic unsaturated ketones and esters without competition from the Mirozoki–Heck reaction. Best results were found with Bedford's palladacycle. The reaction with cyclic derivatives of Garner's aldehyde also took place with high levels of trans diastereoselectivity.
YR 2015
FD 2015
LK https://hdl.handle.net/20.500.14352/115321
UL https://hdl.handle.net/20.500.14352/115321
LA eng
NO Eur. J. Org. Chem. 2015, 1754–1763
DS Docta Complutense
RD 5 abr 2025