RT Journal Article
T1 Increasing dimensionality in self‐assembly. Toward two‐dimensional supramolecular polymers
A1 Atienza Castellanos, Carmen María
A1 Sánchez Martín, Luis
AB Different approaches to achieve 2D supramolecular polymers, as an alternative to the covalent bottom‐up approaches reported for the preparation of 2D materials, are reviewed. The significance of the operation of weak non‐covalent forces to induce a lateral growth of a number of self‐assembling units is collected. The examples of both thermodynamically and kinetically controlled formation of 2D supramolecular polymers showed in this review demonstrate the utility of this strategy to achieve new 2D materials with biased morphologies (nanosheets, scrolls, porous surfaces) and showing elegant applications like chiral recognition, enantioselective uptake or asymmetric organic transformations. Furthermore, elaborated techniques like seeded or living supramolecular polymerizations have been demonstrated to give rise to complex 2D nanostructures.
SN 0947-6539
SN 1521-3765
YR 2024
FD 2024-03-25
LK https://hdl.handle.net/20.500.14352/102623
UL https://hdl.handle.net/20.500.14352/102623
LA eng
NO Chem. Eur. J. 2024
DS Docta Complutense
RD 10 abr 2025