RT Journal Article
T1 Spin–Orbit Coupling Controlled Ground State in the Ir(V) Perovskites A2ScIrO6 (A = Ba or Sr)
A1 Kayser González, Paula
A1 Kennedy, Brendan
A1 Ranjbar, Ben
A1 Kimpton, Justin
A1 Avdeev, Maxim
AB The structural and magnetic properties of the two Ir(V) perovskites Ba2ScIrO6 and Sr2ScIrO6 were established. The structures were refined using a combined neutron and synchrotron data set. At room temperature the former has a cubic structure in space group Fm3̅ m with a = 8.1450(3) Å, and the latter is monoclinic in P21/n with a = 5.6606(3) Å, b = 5.6366(3) Å, c = 7.9720(4) Å, and β = 89.977(5)°. Magnetization measurements show both oxides have magnetic moments close to zero as a consequence of strong spin−orbit coupling that results in a Jeff ≈ 0 ground state. The distortion of the IrO6 octahedra in Sr2ScIrO6 is insufficient to generate crystal field splitting strong enough to quench the spin−orbit coupling
PB Royal Society of Chemistry
SN 0020-1669
YR 2017
FD 2017
LK https://hdl.handle.net/20.500.14352/93611
UL https://hdl.handle.net/20.500.14352/93611
LA eng
NO Paula Kayser, Brendan J. Kennedy, Ben Ranjbar, Justin A. Kimpton, and Maxim Avdeev. Inorganic Chemistry 2017 56 (4), 2204-2209DOI: 10.1021/acs.inorgchem.6b02848
NO Australian Research Council
DS Docta Complutense
RD 9 abr 2025