RT Journal Article
T1 Evidence of three types of short range ordered fluorite structure in the (1 − x) Y0.15Zr0.85O1.93 – x Y0.75Nb0.25O1.75 (0 ≤ x ≤ 1) system
A1 García Martín, Susana
A1 Alario Franco, Miguel Ángel
A1 Fagg, Duncan
A1 Irvine, John
AB The microstructure of the high-temperature quenched oxides of the (1 − x) Y0.15Zr0.85O1.93 – x Y0.75Nb0.25O1.75 (0 ≤ x ≤ 1) system has been investigated by selected area electron diffraction and high resolution transmission electron microscopy. We have found three types of fluorite structure: the x = 0 end member of the solid solution (Y0.15Zr0.85O1.93) shows evidence of tetragonal fluorite-type structure; we have also observed a modulated fluorite-type structure due to short-range ordering of the oxygen vacancies. The microdomain modulated structure gradually evolves from a distorted pyrochlore-type to a type intermediate between C-type and distorted pyrochlore as x decreases from 1 to 0.3.
PB Royal Society of Chemistry
YR 2005
FD 2005-02-22
LK https://hdl.handle.net/20.500.14352/129995
UL https://hdl.handle.net/20.500.14352/129995
LA eng
NO García-Martín, Susana, et al. «Evidence of Three Types of Short Range Ordered Fluorite Structure in the (1 – x) Y0.15Zr0.85O1.93–x Y0.75Nb0.25O1.75(0 ≤x≤ 1) System». Journal of Materials Chemistry, vol. 15, n.o 19, 2005, p. 1903. DOI.org (Crossref), https://doi.org/10.1039/b418557a.
NO Spanish Ministry for Science and Technology
NO Microscopy Centre Luis Bru and the X-ray diffraction C.A.I. from U.C.M.
DS Docta Complutense
RD 19 mar 2026