%0 Journal Article
%A Cano Rico, Israel
%A Gómez-Bengoa, Enrique
%A Landa, Aitor
%A Maestro, Miguel
%A Mielgo, Antonia
%A Olaizola, Iurre
%A Oiarbide, Mikel
%A Palomo, Claudio
%T N-(Diazoacetyl)oxazolidin-2-thiones as Sulfur-Donor Reagents: Asymmetric Synthesis of Thiiranes from Aldehydes
%D 2012
%@ 1433-7851
%U https://hdl.handle.net/20.500.14352/93578
%X We reported the first Rh-catalyzed reaction of a diazoacetyl compound with aldehydes that affords thiiranes, instead of oxiranes, as known before. This unusual reactivity relied on the use of N-(diazoacetyl)oxazolidin-2-thiones as new chiral sulfur-donor reagents and enabled the direct production of optically active thiiranes with very high stereoselectivity.
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