RT Journal Article
T1 Stereodivergent-at-Metal Synthesis of [60]Fullerene Hybrids
A1 Marco Martínez, Juan
A1 Vidal, Sara
A1 Fernández López, Israel
A1 Filippone, Salvatore
A1 Martín, Nazario
AB Chiral fullerene–metal hybrids with complete control over the four stereogenic centers, including the absolute configuration of the metal atom, have been synthesized for the first time. The stereochemistry of the four chiral centers formed during [60]fullerene functionalization is the result of both the chiral catalysts employed and the diastereoselective addition of the metal complexes used (iridium, rhodium, or ruthenium).DFT calculations underpin the observed configurational stability at the metal center, which does not undergo an epimerization process.
PB Wiley Online Library
SN 1433-7851
YR 2017
FD 2017-02-13
LK https://hdl.handle.net/20.500.14352/17678
UL https://hdl.handle.net/20.500.14352/17678
LA eng
NO Unión Europea. FP7
NO Ministerio de Economía y Competitividad (MINECO)
NO Comunidad Autonoma de Madrid
NO Spanish MINECO-FEDER
NO European Research Council (ERC)
DS Docta Complutense
RD 7 abr 2025