RT Journal Article
T1 Molecular architectures of cationic [Pd(g3 -C3H5)(pzbp2py)]+ complexes and BF 4 and CF3SO 3 as counteranions (pzbp2py = 2-[3,5-bis(4-butoxyphenyl)pyrazol-1-yl]pyridine)
A1 Torralba Martínez, María Del Carmen
A1 Cano Esquivel, María Mercedes
A1 Campo Santillana, José Antonio
A1 Heras Castelló, José Vicente
A1 Pinilla Aguilar, Elena
A1 Torres, M.R.
A1 Perles Hernáez, Josefina
A1 Ruiz Valero, Caridad
AB The crystal structures of two complexes containing the 2-[3,5-bis(4-butoxyphenyl)pyrazol-1-yl]pyridine (pzbp2py) ligand bonded to the [Pd(η3-C3H5)]+ fragment and BF4- and CF3 SO3- as counteranions (1 and 2, respectively) have been solved and their molecular architectures compared. The compounds exhibit a 2D network based on weak interactions in which the counterion plays an important role. The molecular layers in the 2D arrangement show interpenetration between the substituent-chains on the pyrazole rings. These features are also observed in related compounds bearing only one chain on the pyrazole ring.
PB Elsevier
SN 0022-328X
YR 2006
FD 2006
LK https://hdl.handle.net/20.500.14352/114525
UL https://hdl.handle.net/20.500.14352/114525
LA eng
NO Torralba, M. C., et al. «Molecular Architectures of Cationic [Pd(Η3-C3H5)(Pzbp2py)]+ Complexes and and as Counteranions (Pzbp2py=2-[3,5-Bis(4-Butoxyphenyl)Pyrazol-1-Yl]Pyridine)». Journal of Organometallic Chemistry, vol. 691, n.o 12, junio de 2006, pp. 2614-22. DOI.org (Crossref), https://doi.org/10.1016/j.jorganchem.2005.12.071
NO Ministerio de Educación y ciencia (España)
NO Comunidad de Madrid
DS Docta Complutense
RD 27 ene 2026