%0 Journal Article
%A Martín, Irene
%A Aragoncillo Abanades, Cristina
%A Almendros Requena, Pedro
%T Palladium‐catalyzed hydroarylation of homopropargyl iodoindoles with concurrent alkyl and iodonium migrations
%D 2021
%@ 1615-4150
%U https://hdl.handle.net/20.500.14352/91934
%X A selective palladium‐catalyzed C-arylation/carbocyclization/iodonium migration reaction sequence has been accomplished. Novel 2‐iodo‐1‐aryl‐9-H‐carbazoles are now easily available. As this result is contrary to the selectivity observed using gold catalysis, the formation of 2‐iodocarbazoles is noticeable, suggesting a metal‐controlled cyclization through chemo‐ and regioselective 1,2‐alkyl migration and 1,4‐iodonium migration.
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