RT Journal Article
T1 Palladium‐catalyzed hydroarylation of homopropargyl iodoindoles with concurrent alkyl and iodonium migrations
A1 Martín, Irene
A1 Aragoncillo Abanades, Cristina
A1 Almendros Requena, Pedro
AB A selective palladium‐catalyzed C-arylation/carbocyclization/iodonium migration reaction sequence has been accomplished. Novel 2‐iodo‐1‐aryl‐9-H‐carbazoles are now easily available. As this result is contrary to the selectivity observed using gold catalysis, the formation of 2‐iodocarbazoles is noticeable, suggesting a metal‐controlled cyclization through chemo‐ and regioselective 1,2‐alkyl migration and 1,4‐iodonium migration.
PB Wiley-WCH GmbH
SN 1615-4150
YR 2021
FD 2021
LK https://hdl.handle.net/20.500.14352/91934
UL https://hdl.handle.net/20.500.14352/91934
LA eng
NO Martín-Mejías I, Aragoncillo C, Almendros P. Palladium-Catalyzed Hydroarylation of Homopropargyl Iodoindoles with Concurrent Alkyl and Iodonium Migrations. Adv. Synth. Catal. 2021, 363, 1449-1456.
NO Ministerio de Ciencia e Innovación (España)
NO European Commission
DS Docta Complutense
RD 6 oct 2024