RT Journal Article T1 Optimization of in situ plasma oxidation of metallic gadolinium thin films deposited by high pressure sputtering on silicon A1 Lucía Mulas, María Luisa A1 Pampillón Arce, María Ángela A1 San Andrés Serrano, Enrique A1 Feijoo Guerrero, Pedro Carlos AB Gadolinium oxide thin films were deposited on silicon by a two-step process: high pressure sputtering from a metallic gadolinium target followed by an in situ plasma oxidation. Several plasma conditions for metal deposition and oxidation were studied in order to minimize the growth of a SiOx layer at the interface between the high permittivity dielectric and the silicon substrate and to avoid substrate damage. Plasma emission was studied with glow discharge optical spectroscopy. The films were structurally characterized by Fourier transform infrared spectroscopy. Metal-insulator-semiconductor capacitors were fabricated with two different top metals (titanium and platinum) to analyze the influence of deposition conditions and the metal choice. Pt gated devices showed an interfacial SiOx regrowth after a forming gas annealing, while Ti gates scavenge the interface layer. PB AVS Amer Inst. Physics SN 1071-1023 YR 2013 FD 2013-01 LK https://hdl.handle.net/20.500.14352/33694 UL https://hdl.handle.net/20.500.14352/33694 LA eng NO 1) C. Auth et al., Intel Technol. J., 12, 77 (2008).2) G.D. Wilk, R.M. Wallace, and J.M. Anthony, J. Appl. Phys., 89, 5243 (2001).3) J. Robertson, Rep. Prog. Phys., 69, 327 (2006).4) C. Zhao et al., Appl. Phys. Lett., 86, 132903 (2005).5) J.M.J. Lopes et al., Microelectron. Eng., 86, 1646 (2009).6) M. Wagner, T. Heeg, J. Schubert, St. Lenk, S. Mantl, C. Zhao, M. Caymax, and S. De Gendt, Appl. Phys. Lett., 88, 172901 (2006).7) M. Roeckerath, J.M.J. Lopes, E. Durgun Özben, C. Sandow, S. Lenk, T. Heeg, J. Schubert, and S. Mantl, Appl. Phys. A: Mater. Sci. Process., 94, 521 (2009).8) K. Fröhlich, J. Fedor, I. Kostic, J. Manka, and P. Ballo, J. Electr. Eng., 62, 54 (2011).9) R.D. Shannon, J. Appl. Phys., 73, 348 (1993).10) J.A. Kittl et al., Microelectron. Eng., 86, 1789 (2009).11) S.-G. Lim et al., J. Appl. Phys., 91, 4500 (2002).12) V. V. Afanasév, A. Stesmans, C. Zhao, M. Caymax, T. Heeg, J. Schubert, Y. Jia, D. G. Schlom, and G. Lucovsky, Appl. Phys. Lett., 85, 5917 (2004).13) B.S. Lim, A. Rahtu, and R.G. Gordon, Nature Mater., 2, 749 (2003).14) G. He, M. Liu, L.Q. Zhu, M. Chang, Q. Fang, and L.D. Zhang, Surf. Sci., 576, 67 (2005).15) E. San Andrés, M. Toledano-Luque, Á. del Prado, M.A. Navacerrada, I. Mártil, G. González-Díaz, W. Bohne, J.R Öhrich, and E. Strub, J. Vac. Sci. Technol. A, 23, 1523 (2005).16) Y. Hoshino, Y. Kido, K. Yamamoto, S. Hayashi, and M. Niwa, Appl. Phys. Lett., 81, 2650 (2002).17) H. Kim, P.C. McIntyre, C.O. Chui, K.C. Saraswat, and S. Stemmer, J. Appl. Phys., 96, 3467 (2004).18) W. Kern and D. Puotinen, RCA Rev., 31, 187 (1970).19) E.H. Nicollian and A. Goetzberger, At&T Tech. J., 46, 1055 (1967).20) J.R. Hauser, CVC version 5.0, © 2000 NCSU Software, Department of Electrical and Computer Engineering, North Carolina State University, Raleigh, NC, 2000.21) W.F. Meggers, C.H. Corliss, and B.F. Scribner, Natl. Bur. Stand. Monograph, 145, 600 (1975).22) G. Norlèn, Phys. Scr., 8, 249 (1973).23) M. Toledano-Luque et al., J. Appl. Phys., 102, 044106 (2007).24) M. Toledano-Luque, M.L. Lucía, Á. del Prado, E. San Andrés, I. Mártil, and G. González-Díaz, Appl. Phys. Lett., 91, 191502 (2007).25) M.A. Pampillón, P.C. Feijoo, E. San Andrés, M. Toledano-Luque, Á. del Prado, A.J. Blázquez, and M.L. Lucía, Microelectron. Eng., 88, 1357 (2011).26) P.G. Pai, S.S. Chao, V. Takagi, and G. Lucovsky, J. Vac. Sci. Technol. A, 4, 689 (1986).27) R.A.B. Devine, Appl. Phys. Lett., 68, 3108 (1996).28) A.C. Diebold, D. Venables, Y. Chabal, D. Muller, M. Weldon, and E. Garfunkel, Mater. Sci. Semicond. Process., 2, 103 (1999).29) E. Monroy et al., Semicond. Sci. Technol., 17, L47 (2002).30) Y. Morita, S. Migita, W. Mizubayashi, and H. Ota, Jpn. J. Appl. Phys., Part 1, 50, 10PG01 (2011).31) E. San Andrés, Á. del Prado, I. Mártil, G. González-Díaz, D. Bravo, and F.J. López, J. Appl. Phys., 92, 1906 (2002). NO © American Vacuum Society. The authors would like to acknowledge C.A.I. de Técnicas Físicas and C.A.I. de Espectroscopía y Espectrometría of the Universidad Complutense de Madrid. This work was funded by the Spanish Ministerio de Economía y Competividad through the project TEC2010-18051. Works of M.A. Pampillón and P.C. Feijoo were funded by the FPI program and FPU Grant No. AP2007-01157, respectively. NO Spanish Ministerio de Economía y Competividad NO FPI program NO FPU program DS Docta Complutense RD 28 abr 2024