RT Journal Article
T1 Trifluoroacetic anhydride promoted tandem conjugate addition of boronic acids/acetal ring opening
A1 Roscales García, Silvia
A1 García Csaky, Aurelio
AB A new stereoselective tandem reaction consisting of the metal-free conjugate addition of boronic acids followed by an intramolecular ring opening of a cyclic acetal has been disclosed. Optically pure polysubstituted tetrahydropyrans have been synthesized diastereoselectively by this new reaction. Two new C–C bonds and up to three stereocenters are formed in a single step, allowing the generation of quaternary stereocenters.
YR 2012
FD 2012
LK https://hdl.handle.net/20.500.14352/114679
UL https://hdl.handle.net/20.500.14352/114679
LA eng
DS Docta Complutense
RD 28 abr 2025