RT Journal Article
T1 Structure sensitivity reaction of chloroform hydrodechlorination to light olefins using Pd catalysts supported on carbon nanotubes and carbon nanofibers
A1 Sichen Liu, 
A1 Carlos Fernandez-Ruiz, 
A1 Ana Iglesias-Juez, 
A1 Martín Martínez, María
A1 Jorge Bedia, 
A1 Carlo Marini, 
A1 Giovanni Agostini, 
A1 Juan José Rodriguez, 
A1 Luisa María Gómez-Sainero, 
AB The upgrading of wasted chloroform in hydrodechlorination for the production of olefins such as ethylene and propylene is studied by employing four catalysts (PdCl/CNT, PdCl/CNF, PdN/CNT, and PdN/CNF) prepared by different precursors (PdCl2 and Pd(NO3)2) supported on carbon nanotubes (CNT) or carbon nanofibers (CNF). TEM and EXAFS-XANES results confirm that Pd nanoparticle size increases in the order: PdCl/CNT < PdCl/CNF ∼ PdN/CNT < PdN/CNF, descending the electron density of Pd nanoparticles in the same order. It illustrates that PdCl-based catalysts show donation of electrons from support to Pd nanoparticles, which is not observed in PdN-based catalysts. Moreover, this effect is more evident in CNT. The smallest and well-dispersed Pd nanoparticles (NPs) on PdCl/CNT with high electron density favor an excellent and stable activity and a remarkable selectivity to olefins. In contrast, the other three catalysts show lower selectivity to olefins and lower activities which suffer strong deactivation due to the formation of Pd carbides on their larger Pd nanoparticles with lower electron density, compared to PdCl/CNT
PB Elsevier
SN 0021-9797
YR 2023
FD 2023-10
LK https://hdl.handle.net/20.500.14352/107206
UL https://hdl.handle.net/20.500.14352/107206
LA eng
NO Sichen Liu, Carlos Fernandez-Ruiz, Ana Iglesias-Juez, Maria Martin-Martinez, Jorge Bedia, Carlo Marini, Giovanni Agostini, Juan José Rodriguez, Luisa María Gómez-Sainero, Structure sensitivity reaction of chloroform hydrodechlorination to light olefins using Pd catalysts supported on carbon nanotubes and carbon nanofibers, Journal of Colloid and Interface Science, Volume 648, 2023, Pages 427-439, ISSN 0021-9797, https://doi.org/10.1016/j.jcis.2023.05.169.
DS Docta Complutense
RD 26 ago 2024