RT Journal Article
T1 Transition-Metal-Free Reactions of Boronic Acids: 1,3-Stereochemical Induction in the Substrate-Controlled Conjugate Addition
A1 Roscales García, Silvia
A1 Maroto Ortega, Víctor Manuel
A1 García Csaky, Aurelio
AB The substrate-controlled 1,3-stereoselective conjugate addition of boronic acids and potassium trifluoroborates under metal-free conditions has been developed. This reaction affords bicyclic acetals, which have been used as key intermediates in the stereodivergent synthesis of polysubstituted tetrahydropyrans.
PB American Chemical Society
YR 2013
FD 2013
LK https://hdl.handle.net/20.500.14352/116154
UL https://hdl.handle.net/20.500.14352/116154
LA eng
NO Roscales, Silvia, et al. «Transition-Metal-Free Reactions of Boronic Acids: 1,3-Stereochemical Induction in the Substrate-Controlled Conjugate Addition». The Journal of Organic Chemistry, vol. 78, n.o 24, diciembre de 2013, pp. 12825-30. DOI.org (Crossref), https://doi.org/10.1021/jo402262m.
NO Ministerio de Ciencia e Innovación (España)
DS Docta Complutense
RD 4 oct 2025