RT Journal Article
T1 Linear One-Dimensional Coordination Polymers Constructed by Dirhodium Paddlewheel and Tetracyanido-Metallate Building Blocks
A1 Prior, David
A1 Cortijo Montes, Miguel
A1 González Prieto, Rodrigo
A1 Herrero Domínguez, Santiago
A1 Jiménez Aparicio, Reyes
A1 Perles Hernáez, Josefina
A1 Priego Bermejo, José Luis
AB In this article, we describe the preparation of anionic heteronuclear one-dimensional coordination polymers made by dirhodium paddlewheels and tetracyanido-metallatate building blocks. A series of complexes of (PPh4)2n[{Rh2(µ-O2CCH3)4}{M(CN)4}]n (M = Ni (1), Pd (2), Pt (3)) formulae were obtained by reaction of [Rh2(μ-O2CCH3)4] with (PPh4)2[M(CN)4] in a 1:1 or 2:1 ratio. Crystals of 1−3 suitable for single crystal X-ray diffraction were grown by slow diffusion of a dichloromethane solution of the dirhodium complex into a chloroform solution of the corresponding tetracyanido–metallatate salt. Compounds 1 and 2 are isostructural and crystallize in the triclinic P-1 space group, while compound 3 crystallizes in the monoclinic P21/n space group. A detailed description of the structures is presented, including the analysis of the packing of anionic chains and PPh4+ cations.
PB MDPI
SN 2073-4352
YR 2019
FD 2019-11-23
LK https://hdl.handle.net/20.500.14352/8248
UL https://hdl.handle.net/20.500.14352/8248
LA eng
NO Ministerio de Economía y Competitividad (MINECO)
NO Comunidad de Madrid
DS Docta Complutense
RD 4 oct 2024