%0 Journal Article
%A Julián Ortega, Inmaculada
%A Sáez Puche, Regino
%A Romero de Paz, Julio
%A Martínez, José Luis
%T Structural characterisation and spin glass behaviour of the new oxide Ba2ScCoO5
%D 1999
%@ 0959-9428
%U https://hdl.handle.net/20.500.14352/94275
%X The new oxide Ba 2 ScCoO 5 has been synthesised by solid state reaction and characterised by using both X-ray and electron diffraction techniques. It crystallises in a perovskite-type structure, showing cubic symmetry, space group Pm[3 with combining macron]m [a=4.1400(9) Å]. χ dc and χ ac magnetic susceptibility have been measured down to 1.6 K and analysed, indicating the existence of a freezing phenomenon corresponding to a spin glass state. In the high temperature range, χ dc shows a Curie-Weiss like behaviour, with magnetic correlations starting around T C =50 K. Below this temperature, a strong irreversibility in χ vs. T curves obtained by zero field cooled and field cooled processes (ZFC/FC) has been detected. A second magnetic transition to a spin-glass phase is observed at T F =35 K in the ZFC curve. χ ac measurements performed at different frequencies and magnetic fields also show all the common features characteristic of re-entrant spin-glasses. A possible origin of this magnetic behaviour is proposed and discussed.
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