RT Journal Article
T1 Macromolecular features of lignin, hemicellulose and cellulose fractions from biphasic organosolv fractionation of diverse biomasses: A comparative study
A1 González, Saúl
A1 Rodríguez, Pablo
A1 Rigual Hernández, Victoria de los Ángeles
A1 Rivas, Sandra
AB Understanding lignocellulosic biomass (LB) fractionation is crucial for integrated valorization pathways. Eucalyptus (EW), pine (PW), hazelnut shells (HS) and vine pruning (VP) were selected as representative LB for “onestep” fractionation in biphasic media of water and 1-butanol or 1-pentanol by microwave heating. Owing to thelimited water solubility of these alcohols, the reaction media was constituted by an aqueous phase (hemicellulose-derived products), an organic phase (mainly lignin) and a solid (mainly cellulose). Equivalent operationalconditions enabled the evaluation of LB types and solvents based on phase composition and yields. EW exhibitedthe highest fractionation efficiency and high cellulose recoveries, and almost complete hemicellulose solubilization were consistently achieved in processed solids. 1-pentanol systems yielded higher recoveries ofhemicellulose-derived saccharides in the aqueous phase, compared to 1-butanol. Oppositely, lower delignification was observed for LB in 1-pentanol systems, highlighting the solvent’s role. Lignins extracted with 1-pentanolpreserved a higher proportion of β-O-4 interunit linkages and lower molecular weights compared with 1-butanol.Consequently, phenylcoumaran and resinol interunit linkages are present in higher abundance in 1-butanollignins. This comparative study highlights the role of solvent-feedstock interactions in determining the recovery and features of cellulose, hemicellulose and lignin, contributing to a rational design of integrated biorefinerystrategies.
PB Elsevier
YR 2025
FD 2025-08-13
LK https://hdl.handle.net/20.500.14352/123504
UL https://hdl.handle.net/20.500.14352/123504
LA eng
NO Saúl González, Pablo Rodríguez, Victoria Rigual, Sandra Rivas, Macromolecular features of lignin, hemicellulose and cellulose fractions from biphasic organosolv fractionation of diverse biomasses: A comparative study, International Journal of Biological Macromolecules, Volume 322, Part 2, 2025, 146865, ISSN 0141-8130, https://doi.org/10.1016/j.ijbiomac.2025.146865.
NO Consellería de Cultura, Educación, Formación Profesional e Universidades (Xunta de Galicia)
NO Universidade de Vigo
DS Docta Complutense
RD 27 dic 2025