RT Journal Article
T1 Copper Complexes with New Pyridylpyrazole Based Ligands
A1 Campo Santillana, José Antonio
A1 Cano Esquivel, María Mercedes
A1 Heras Castelló, José Vicente
A1 Lagunas, M. Cristina
A1 Perles Hernáez, Josefina
A1 Pinilla Aguilar, Elena
A1 Torres, María del Rosario
AB We report the synthesis, characterization, and crystal structures of new ligands of the pyridinylpyrazole type, i.e., 3,5-bis(4-butoxyphenyl)-1-(pyridin-2-yl)-1H-pyrazole (L1) and 3,5-bis(4-phenoxyphenyl)-1-(pyridin-2-yl)-1H-pyrazole (L2) (Scheme 1), and the study of their coordination behavior towards CuI and CuII. The versatility of this type of ligand, which can give access to different coordination spheres about the metal center, depending on the nature of the copper starting material used in the preparation of the complexes (Scheme 2), is illustrated. Thus, pseudo-tetrahedral CuI as well as six-coordinated tetragonal and distorted tetragonal pyramidal CuII derivatives were obtained for [Cu(L)2]PF6, [Cu(Cl)2(L)2] (L=L1, L2), and [Cu(Cl)(L1)2]PF6, respectively. We also present a crystallographic support of a distorted octahedral cis-bis(tetrafluoroborato-κF)copper(II) compound found for [Cu(BF4)2(L1)2] (3).
PB Wiley
SN 0018-019X
YR 2002
FD 2002
LK https://hdl.handle.net/20.500.14352/134677
UL https://hdl.handle.net/20.500.14352/134677
LA eng
NO Campo, José A., et al. «Copper Complexes with New Pyridylpyrazole Based Ligands». Helvetica Chimica Acta, vol. 85, n.º 4, abril de 2002, p. 1079. DOI.org (Crossref), https://doi.org/10.1002/1522-2675(200204)85:4%3C1079::AID-HLCA1079%3E3.0.CO;2-G.
NO Ministerio de Educación y Ciencia (España)
DS Docta Complutense
RD 15 abr 2026