RT Journal Article
T1 Enantiospecific synthesis of substituted 1-norbornanesulfonic acids and 1-norbornanesulfenic and sulfonic acid derivatives
A1 Garcı́a Martı́nez, Antonio
A1 Teso Vilar, Enrique
A1 Moreno Jiménez, Florencio
A1 Garcı́a Amo, María
AB New homochiral 1-norbornanesulfenic and sulfonic acid derivatives 2–7, as well as the sulfonic acids 8, are easily synthesised starting from 2-methylene-1-norbornylthiotriflates 1. This new class of homochiral bridgehead thiosulfonates was prepared by us from naturally occurring (+)-camphor and (−)-fenchone. Nucleophilic substitution at the sulfenyl sulfur atom is the key step for this synthetic strategy
PB Elsevier science Ltd.
SN 0957-4166
YR 2000
FD 2000-05-05
LK https://hdl.handle.net/20.500.14352/58169
UL https://hdl.handle.net/20.500.14352/58169
LA eng
NO Received 23 November 1999; revised 22 March 2000; accepted 24 March 2000
NO Dirección General de Investigación Científica y Técnica (España)
DS Docta Complutense
RD 17 abr 2025