RT null
T1 On-surface covalent synthesis of carbon nanomaterials by harnessing carbon gem-polyhalides
A1 Urgel, José I.
A1 Sánchez Grande, Ana
A1 Vicent, Diego J.
A1 Jelínek, Pavel
A1 Martín León, Nazario
A1 Écija, David
AB The design of innovative carbon-based nanostructures stands at the forefront of both chemistry and materials science. In this context, π-conjugated compounds are of great interest due to their impact in a variety of fields, including optoelectronics, spintronics, energy storage, sensing and catalysis. Despite extensive research efforts, substantial knowledge gaps persist in the synthesis and characterization of new π-conjugated compounds with potential implications for science and technology. On-surface synthesis has emerged as a powerful discipline to overcome limitations associated with conventional solution chemistry methods, offering advanced tools to characterize the resulting nanomaterials. This review specifically highlights recent achievements in the utilization of molecular precursors incorporating carbon geminal (gem)-polyhalides as functional groups to guide the formation of π-conjugated 0D species, as well as 1D, quasi-1D π-conjugated polymers, and 2D nanoarchitectures. By delving into reaction pathways, novel structural designs, and the electronic, magnetic, and topological features of the resulting products, the review provides fundamental insights for a new generation of π-conjugated materials.
PB Wiley
YR 2024
FD 2024
LK https://hdl.handle.net/20.500.14352/120455
UL https://hdl.handle.net/20.500.14352/120455
LA eng
NO Urgel, José I., et al. «On‐Surface Covalent Synthesis of Carbon Nanomaterials by Harnessing Carbon Gem‐ Polyhalides». Advanced Materials, vol. 36, n.o 33, agosto de 2024, p. 2402467. https://doi.org/10.1002/adma.202402467.
NO Ministerio de Ciencia, Innovación y Universidades (España) 
NO Comunidad de Madrid
DS Docta Complutense
RD 21 ene 2026