RT Journal Article
T1 Low-Lanthanide-Content CeO2/MgO Catalysts with Outstandingly Stable Oxygen Storage Capacities: An In- Depth Structural Characterization by Advanced STEM Techniques
A1 Tinoco Rivas, Miguel
A1 Sánchez, Juan José
A1 Yeste, Pilar
A1 López Haro, Miguel
A1 Trasobares, Susana
A1 Hungría, Ana Belén
A1 Bayle-Guillemaud, Pascale
A1 Blanco, Ginesa
A1 Pintado, José María
A1 Calvino, José Juan
AB A novel CeO2/MgO catalyst with low ceria loading has been synthesized. This catalyst showed unique redox properties compared with conventional high and low surface area CeO2. Advanced (scanning) transmission electron microscopy techniques revealed the presence of a variety of highly dispersed ceria nanostructures: isolated CeOx entities, CeO2 clusters, as well as fairly small (<5 nm) CeO2 nanoparticles. More interestingly, this CeO2/MgO catalyst showed outstanding stability in its redox response against high temperature aging treatments. Thus, after reduction in hydrogen at 950 °C and further oxidation at 500 °C, CeO2 reduction effects took still place at low temperatures, and no significant loss of oxygen storage capacity (OSC) was detected. Unique ceria-bilayer nanostructures were found and characterized in the aged catalyst. Their peculiar structural and chemical properties seem to be responsible for the large improvement observed in the stability of the redox response.
SN 1867-3880
YR 2015
FD 2015
LK https://hdl.handle.net/20.500.14352/94740
UL https://hdl.handle.net/20.500.14352/94740
LA eng
NO Tinoco, Miguel, et al. «Low‐Lanthanide‐Content CeO 2 /MgO Catalysts with Outstandingly Stable Oxygen Storage Capacities: An In‐Depth Structural Characterization by Advanced STEM Techniques». ChemCatChem, vol. 7, n.o 22, noviembre de 2015, pp. 3763-78. https://doi.org/10.1002/cctc.201500855.
NO Junta de Andalucía
NO European Commission
NO Ministerio de Ciencia e Innovación (España)
DS Docta Complutense
RD 30 dic 2025