RT Journal Article
T1 Modulating the Differentiation of Kinetically Controlled Supramolecular Polymerizations through the Alkyl Bridge Length
A1 Naranjo Calderón, Cristina
A1 Adalid, Sergio
A1 Gómez Aspe, Rafael
AB The synthesis and self-assembling features of N-annulated perylenebisimides (N-PBIs) 2-4 are reported and compared with the complex self-assembly of N-PBI 1. The studies presented herein demonstrate that increasing the length of the alkyl spacer separating the central aromatic core of the dye and the peripheral side chains cancels the differentiation on the corresponding supramolecular polymerization. Thus, only 2 is able form two different supramolecular polymorphs. The formation of kinetically trapped monomeric species is observed for all the N-PBIs 2-4. These metastable species, constituted by intramolecularly H-bonded pseudocycles of 7, 8, 9 or 10 members for compounds 1, 2, 3 and 4, respectively, provoke kinetically controlled supramolecular polymerizations that can be accelerated by the addition of seeds. The results presented herein shed light on the intricate process of differentiation in self-assembly.
PB Wiley-Vch
SN 1433-7851
YR 2023
FD 2023
LK https://hdl.handle.net/20.500.14352/72926
UL https://hdl.handle.net/20.500.14352/72926
LA eng
NO Naranjo, Cristina, et al. «Modulating the Differentiation of Kinetically Controlled Supramolecular Polymerizations through the Alkyl Bridge Length». Angewandte Chemie International Edition, vol. 62, n.o 14, marzo de 2023, p. e202218572. DOI.org (Crossref), https://doi.org/10.1002/anie.202218572.
NO Ministerio de Ciencia, Innovación y Universidades (España)
NO Comunidad de Madrid
DS Docta Complutense
RD 6 abr 2025