RT Journal Article
T1 Synthesis and electronic properties of nitrogen-doped π-extended polycyclic aromatic dicarboximides with multiple redox processes
T2 Síntesis y propiedades electrónicas de dicarboximidas aromáticas policíclicas π-extendidas dopadas con nitrógeno con procesos redox múltiples
A1 Alonso-Navarro, Matías J.
A1 Harbuzaru, Alexandra
A1 Martínez-Fernández, Marcos
A1 Pérez Camero, Paula
A1 López Navarrete, J. Teodomiro
A1 Ramos, M. Mar
A1 Ponce Ortiz, Rocío
A1 Segura Castedo, José Luis
AB In this work, a series of nitrogen-doped polycyclic aromatic mono and dicarboximides was designed, and their synthesis is reported by an innovative synthetic procedure that avoids metal-based cross-coupling reactions. A combined theoretical, electrochemical, optical spectroscopy and material characterization study allows the investigation of the interplay of different effects such as (i) the type of solubilizing chain, (ii) the all-acceptor vs. donor–acceptor nature of the novel systems, and (iii) the molecular ordering, on the ability to stabilize multiple charges and on the OTFT device response characteristics. The amphoteric redox behavior of some of the novel systems allow to obtain ambipolar mobilities while the electron mobility values of the three all-acceptor systems can be rationalized in terms of supramolecular aggregation and enhanced film-forming ability.
PB Royal Society of Chemistry
SN 2050-7526
SN 2050-7534
YR 2021
FD 2021-06-02
LK https://hdl.handle.net/20.500.14352/100915
UL https://hdl.handle.net/20.500.14352/100915
LA eng
NO Alonso-Navarro, M. J., Harbuzaru, A., Martínez-Fernández, M., Camero, P. P., Navarrete, J. T. L., Ramos, M. M., ... & Segura, J. L. (2021). Synthesis and electronic properties of nitrogen-doped π-extended polycyclic aromatic dicarboximides with multiple redox processes. Journal of Materials Chemistry C, 9(25), 7936-7949.
NO This work was financially supported by MICINN (PID2019-106268GB-C33) and the UCM (INV.GR.00.1819.10759). MJAN gratefully acknowledges Universidad Rey Juan Carlos for a predoctoral contract. The university of Málaga acknowledges support from Junta de Andalucía (projects UMA18-FEDERJA-080 and P18-FR-4559) and MICINN (PID2019-110305GB-I00). RPO and AH also thank the Research Central Services (SCAI) of the University of Málaga and especially the Vibrational Spectroscopy Laboratory.
NO MICINN
NO Universidad Complutense de Madrid
NO Universidad Rey Juan Carlos
NO Universidad de Málaga
NO Junta de Andalucía
DS Docta Complutense
RD 25 jul 2024