2026-06-28T15:31:15Zhttps://docta.ucm.es/rest/oai/request

oai:docta.ucm.es:20.500.14352/1004002026-06-10T11:03:07Zcom_20.500.14352_14col_20.500.14352_15

Following the light: 3D-printed COF@poly(2-hydroxyethyl methacrylate) dual emissive composite with response to polarity and acidity Martínez-Fernández, Marcos Gavara, Raquel Royuela Collado, Sergio Fernández-Ecija, Laura Ignacio Martínez, José Zamora, Félix Segura Castedo, José Luis “María de Maeztu” Programme for Units of Excellence in R&D (CEX2018-000805-M) A new imine-based covalent organic framework (COF) functionalized in its cavities with moieties of the chromophore Nile Red has been synthesized and characterized. Using mechanical (ultrasonics) and chemical (acid-self-exfoliation) methods, exfoliation of the COF powder has been explored in water and water/organic media. In the latter, the obtained colloids exhibit dual emission originating from the Nile Red units (red) and the COF framework (green) that can be employed to prepare ratiometric sensors of polarity and acidity. Thus, taking advantage of the in situ exfoliation of the material in methacrylic monomers, free-standing polymeric films that preserve the optical properties of the exfoliated COF have been prepared. Finally, 3D liquid crystal display (LCD) additive manufacturing has been employed to prepare the dual emissive composites as tailored 3D-printed objects. 2024-02-08T12:20:14Z 2024-02-08T12:20:14Z 2022 journal article Martínez-Fernández, Marcos, et al. «Following the Light: 3D-Printed COF@poly(2-Hydroxyethyl Methacrylate) Dual Emissive Composite with Response to Polarity and Acidity». Journal of Materials Chemistry A, vol. 10, n.o 9, 2022, pp. 4634-43. https://doi.org/10.1039/D1TA09614A. 2050-7488 10.1039/d1ta09614a https://hdl.handle.net/20.500.14352/100400 2050-7496 https://doi.org/10.1039/D1TA09614A eng info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2019-106268GB-C32/ES/DISEÑO DE MATERIALES 2D PARA APLICACIONES DE ENERGIA: MEMBRANAS Y BATERIAS/ info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2019-106268GB-C33/ES/DISEÑO DE MATERIALES 2D PARA APLICACIONES EN ENERGIA: REDES ORGANICAS COVALENTES/ info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2020-113142RB-C21/ES/SINTESIS Y CARACTERIZACION "BOTTOM-UP" DE NANOMATERIALES A MEDIDA CON FUNCIONALIDADES AVANZADAS/ S2018/NMT-4367/FOTOART open access Royal Society of Chemistry