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oai:docta.ucm.es:20.500.14352/1072062025-03-18T15:32:57Zcom_20.500.14352_14col_20.500.14352_15

00925njm 22002777a 4500 dc Liu, Sichen author Fernandez-Ruiz, Carlos author Iglesias-Juez, Ana author Martín Martínez, María author Bedia, Jorge author Marini, Carlo author Agostini, Giovanni author Rodriguez, Juan José author Gómez-Sainero, Luisa María author 2023 The upgrading of wasted chloroform in hydrodechlorination for the production of olefins such as ethylene and propylene is studied by employing four catalysts (PdCl/CNT, PdCl/CNF, PdN/CNT, and PdN/CNF) prepared by different precursors (PdCl2 and Pd(NO3)2) supported on carbon nanotubes (CNT) or carbon nanofibers (CNF). TEM and EXAFS-XANES results confirm that Pd nanoparticle size increases in the order: PdCl/CNT < PdCl/CNF ∼ PdN/CNT < PdN/CNF, descending the electron density of Pd nanoparticles in the same order. It illustrates that PdCl-based catalysts show donation of electrons from support to Pd nanoparticles, which is not observed in PdN-based catalysts. Moreover, this effect is more evident in CNT. The smallest and well-dispersed Pd nanoparticles (NPs) on PdCl/CNT with high electron density favor an excellent and stable activity and a remarkable selectivity to olefins. In contrast, the other three catalysts show lower selectivity to olefins and lower activities which suffer strong deactivation due to the formation of Pd carbides on their larger Pd nanoparticles with lower electron density, compared to PdCl/CNT Sichen Liu, Carlos Fernandez-Ruiz, Ana Iglesias-Juez, Maria Martin-Martinez, Jorge Bedia, Carlo Marini, Giovanni Agostini, Juan José Rodriguez, Luisa María Gómez-Sainero, Structure sensitivity reaction of chloroform hydrodechlorination to light olefins using Pd catalysts supported on carbon nanotubes and carbon nanofibers, Journal of Colloid and Interface Science, Volume 648, 2023, Pages 427-439, ISSN 0021-9797, https://doi.org/10.1016/j.jcis.2023.05.169. 0021-9797 10.1016/j.jcis.2023.05.169 https://hdl.handle.net/20.500.14352/107206 https://doi.org/10.1016/j.jcis.2023.05.169 https://www.sciencedirect.com/science/article/pii/S0021979723009694 Structure sensitivity reaction of chloroform hydrodechlorination to light olefins using Pd catalysts supported on carbon nanotubes and carbon nanofibers