2026-06-29T08:02:05Zhttps://docta.ucm.es/rest/oai/request

oai:docta.ucm.es:20.500.14352/1092242025-09-18T15:37:02Zcom_20.500.14352_14col_20.500.14352_15

Full control of the orientation of non-symmetric molecules using weak and moderate electric fields González Férez, Rosario Omiste Romero, Juan José Física (Química) Ciencias 2210 Química Física 2024 Acuerdos transformativos CRUE We investigate the full control over the orientation of a planar non-symmetric molecule by using moderate and weak electric fields. Quantum optimal control techniques allow us to orient any axis of 6-chloropyridazine-3-carbonitrile, which is taken as prototype example here, along the electric field direction. We perform a detailed analysis by exploring the impact on the molecular orientation of the time scale and strength of the control field. The underlying physical phenomena allowing for the control of the orientation are interpreted in terms of the frequencies contributing to the field-dressed dynamics and to the driving field by a spectral analysis. Comunidad de Madrid Junta de Andalucía Ministerio de Ciencia, Innovación y Universidades (España) Universidad de Granada (España) Depto. de Química Física Fac. de Ciencias Químicas TRUE pub 2024-10-22T10:58:33Z 2024-10-22T10:58:33Z 2024 journal article VoR https://hdl.handle.net/20.500.14352/109224 XXXX-XXXX 10.1039/d3cp05592b 1463-9084 eng info:eu-repo/grantAgreement/CAM/Plan Regional de Investigación Científica e Innovación Tecnológica/PR27/21-010 info:eu-repo/grantAgreement/MICIN//PID2019-105458RBI00 info:eu-repo/grantAgreement/MICIN//PID2021-122839NB-I00 info:eu-repo/grantAgreement/MICIN//PID2020-113390GB-I00 info:eu-repo/grantAgreement/Junta de Andalucía//PY20-00082 info:eu-repo/grantAgreement/European Regional Development Fund-Universidad de Granada//A-FQM-52-UGR20 R. González-Férez and J. J. Omiste, Full control of the orientation of non-symmetric molecules using weak and moderate electric fields, Phys. Chem. Chem. Phys., 2024, 26, 4533–4540. Attribution-NonCommercial 4.0 International http://creativecommons.org/licenses/by-nc/4.0/ open access application/pdf Royal Society of Chemistry