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oai:docta.ucm.es:20.500.14352/1127212024-12-18T00:50:42Zcom_20.500.14352_14col_20.500.14352_15

Understanding the reactivity of frustrated Lewis pairs with the help of the activation strain model–energy decomposition analysis method Fernández López, Israel This Feature article presents recent representative applications of the combination of the Activation Strain Model of reactivity and the Energy Decomposition Analysis methods to understand the reactivity of Frustrated Lewis Pairs (FLPs). This approach has been helpful to not only gain a deeper quantitative insight into the factors controlling the cooperative action between the Lewis acid/base partners but also to rationally design highly active systems for different bond activation reactions. Issues such as the influence of the nature of the FLP antagonists or the substituents directly attached to them on the reactivity are covered herein, which are crucial for the future development of this fascinating family of compounds. 2024-12-17T09:03:41Z 2024-12-17T09:03:41Z 2022-03-21 journal article Israel Fernández, Understanding the reactivity of frustrated Lewis pairs with the help of the activation strain model–energy decomposition analysis method, Chemical Communications, Volume 58, Issue 32, 2022, Pages 4931-4940, ISSN 1359-7345, https://doi.org/10.1039/d2cc00233g. (https://www.sciencedirect.com/science/article/pii/S1359734522012587) 10.1039/d2cc00233g https://hdl.handle.net/20.500.14352/112721 https://doi.org/10.1039/d2cc00233g https://pubs.rsc.org/en/content/articlelanding/2022/cc/d2cc00233g eng info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2019-106184GB-I00/ES/UNA APROXIMACION DIFERENTE PARA ENTENDER Y CONTROLAR LA CATALISIS/ RED2018- 102387-T http://creativecommons.org/licenses/by-nc-nd/4.0/ restricted access Attribution-NonCommercial-NoDerivatives 4.0 International RSC