2026-06-29T01:19:00Zhttps://docta.ucm.es/rest/oai/requestoai:docta.ucm.es:20.500.14352/1138442025-07-17T16:42:41Zcom_20.500.14352_14col_20.500.14352_15
Control defeasance by anti-alignment in the excited state
Chang, Bo Y
Shin, Seokmin
González Vázquez, Jesús
Martín, Fernando
Malinovsky, Vladimir S
Sola, Ignacio R
We predict anti-alignment dynamics in the excited state of H2+ or related homonuclear dimers in the presence of a strong field. This effect is a general indirect outcome of the strong transition dipole and large polarizabilities typically used to control or to induce alignment in the ground state. In the excited state, however, the polarizabilities have the opposite sign compared to those in the ground state, generating a torque that aligns the molecule perpendicular to the field, deeming any laser-control strategy impossible.
2025-01-13T08:39:35Z
2025-01-13T08:39:35Z
2025-01-13T08:39:35Z
2019
journal article
https://hdl.handle.net/20.500.14352/113844
XXXX-XXXX
10.1039/c9cp04427b
eng
CTQ2015- 65033-P
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PGC2018-096444-B-I00/ES/DINAMICA DE REACCIONES QUIMICAS Y NANOMATERIALES INDUCIDA POR IRRADIACION LASER ULTRARRAPIDA/
FIS2016-77889-R
Y2018/NMT-5028
Chang BY , Shin S , González-Vázquez J , Martín F , Malinovsky VS , Sola IR . Control defeasance by anti-alignment in the excited state. Phys Chem Chem Phys. 2019 Nov 14;21(42):23620-23625. doi: 10.1039/c9cp04427b. Epub 2019 Oct 18. PMID: 31624812.
http://creativecommons.org/licenses/by-nc-nd/4.0/
restricted access
Attribution-NonCommercial-NoDerivatives 4.0 International