2026-06-08T23:15:43Zhttps://docta.ucm.es/rest/oai/request

oai:docta.ucm.es:20.500.14352/1161752025-03-18T13:39:35Zcom_20.500.14352_14col_20.500.14352_15

Transition-Metal-Free Direct anti-Carboboration of Alkynes with Boronic Acids To Produce Alkenylheteroarenes Roscales García, Silvia García Csaky, Aurelio The transition-metal-free intermolecular direct 1,2-carboboration reaction of heteroarylacetylenes using boronic acids as reagents is achieved by utilizing tartaric acid as promoter. The reaction proceeds with excellent regioselectivity and anti stereoselectivity to afford boroxole frameworks. The resulting compounds are of use for the stereoselective preparation of polysubstituted alkenylheteroarenes. 2025-01-27T09:14:10Z 2025-01-27T09:14:10Z 2015 journal article Roscales, Silvia, y Aurelio G. Csákÿ. «Transition-Metal-Free Direct Anti -Carboboration of Alkynes with Boronic Acids To Produce Alkenylheteroarenes». Organic Letters, vol. 17, n.o 6, marzo de 2015, pp. 1605-08. DOI.org (Crossref), https://doi.org/10.1021/acs.orglett.5b00517. 10.1021/acs.orglett.5b00517 https://hdl.handle.net/20.500.14352/116175 https://doi.org/10.1021/acs.orglett.5b00517 eng restricted access American Chemical Society