2026-06-07T23:48:19Zhttps://docta.ucm.es/rest/oai/request

oai:docta.ucm.es:20.500.14352/121762026-01-26T13:15:58Zcom_20.500.14352_14col_20.500.14352_15

00925njm 22002777a 4500 dc Agmon, Liron author Shahar, Itai author Yosufov, Danny author Pimentel Guerra, Carlos author Pina Martínez, Carlos Manuel author Gnecco, Enrico author Berkovich, Ronen author 2018-03-16 Friction force microscopy (FFM) in aqueous environments has recently proven to be a very effective method for lattice-resolution imaging of crystal surfaces. Here we demonstrate the use of ethanol for similar measurements on water-soluble materials. Lattice resolved frictional stick-slip traces of a cleaved NaCl(100) surface submerged in ethanol are compared with previous obtained FFM results in ultrahigh vacuum (UHV). We use the Prandtl-Tomlinson framework to estimate the amplitude of the corrugation potential and the contact stiffness. The surface potential amplitude scales with the applied normal loads are in good agreement with data obtained for NaCl measured under UHV conditions, but demonstrates deviations from the ideal periodic potential given by the Prandtl-Tomlinson model. An additional finding is that the use of ethanol allows us to explore higher load ranges without detectable evidence of surface wear. The contact stiffness does not vary significantly with the normal load up to 38 nN, while above it a sudden increase by almost one order of magnitude was observed. Comparing this to previous results suggests that considerable atom rearrangements may occur in the contact region, although the (100) surface structure is preserved by ethanol-assisted diffusion of Na and Cl ions. ISSN: 2045-2322, online ISSN: 2045-2322 10.1038/s41598-018-22847-z https://hdl.handle.net/20.500.14352/12176 https://www.nature.com/articles/s41598-018-22847-z https://www.nature.com/ Estimation of interaction energy and contact stiffness in atomic-scale sliding on a model sodium chloride surface in ethanol