2026-06-29T08:19:44Zhttps://docta.ucm.es/rest/oai/request

oai:docta.ucm.es:20.500.14352/1349082026-04-21T23:55:18Zcom_20.500.14352_14col_20.500.14352_15

Catalyst-free insertion of carbon monoxide into terminal Mg–C(sp3) bonds Kubisz, M. Fernández López, Israel Hadlington, T. J. 547 Química 23 Química We describe the catalyst-free Insertion of carbon monoxide (CO) into magnesium alkyl bonds, leading exclusively to enediolate compounds through C–C coupling. Computational investigations suggest a metallated ketene intermedate. Ultimately, the formed enedoliate fragment can be liberated on reaction with a silane, establishing a potential pathway for s-block metal alkyl formylation catalysis. Ministerio de Ciencia e Inovación (España) Agencia Estatal de Investigación (España) Depto. de Química Orgánica Fac. de Ciencias Químicas TRUE pub 2026-04-21T06:51:10Z 2026-04-21T06:51:10Z 2026-03-07 journal article VoR https://hdl.handle.net/20.500.14352/134908 XXXX-XXXX 10.1039/d6cc00736h eng info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/PID2022-139318NB-I00/ES/ENTENDIENDO LOS FACTORES QUE CONTROLAN LA REACTIVIDAD EN GRUPOS PRINCIPALES/ Project 101076897 – SINGAMBI Project Nr. 523956566 Kubisz, M., et al. «Catalyst-Free Insertion of Carbon Monoxide into Terminal Mg–C(Sp3 ) Bonds». Chemical Communications, vol. 62, n.o 29, 2026, pp. 7519-23. DOI.org (Crossref), https://doi.org/10.1039/D6CC00736H. Attribution-NonCommercial-NoDerivatives 4.0 International http://creativecommons.org/licenses/by-nc-nd/4.0/ open access application/pdf RSC