2026-06-29T08:14:02Zhttps://docta.ucm.es/rest/oai/requestoai:docta.ucm.es:20.500.14352/135382024-09-24T13:33:08Zcom_20.500.14352_14col_20.500.14352_15
FormylBODIPYs by PCC-Promoted Selective Oxidation of α-MethylBODIPYs. Synthetic Versatility and Applications
Ramos Torres, Ágata
Avellanal Zaballa, Edurne
Prieto Castañeda, Alejandro
García Garrido, Fernando
Bañuelos Prieto, Jorge
Rodríguez Agarrabeitia, Antonia
Ortiz García, María Josefa
547.1
543.426
FormylBODIPYs
MethylBODIPYs
BODIPYs
Fluorescence sensors
Photosensitizers
Química orgánica (Química)
2306 Química Orgánica
Received: 26/04/2019; Published: 10/06/2019
An efficient synthesis of formylBODIPYs has been established based on an oxidation with PCC of 3-methylBODIPYs. It has been demonstrated that this reagent can oxidize methyl groups at such position of the BODIPY core, regardless of its substitution pattern. Moreover, through this procedure it is possible to synthesize 8-aryl-3,5-diformylBODIPYs, which are otherwise difficult to obtain. These precursors have been functionalized to develop fluorescent sensors of amino acids or photosensitizers for singlet oxygen generation.
Ministerio de Economía y Competitividad (MINECO)
Gobierno Vasco
Sección Deptal. de Química Orgánica (Óptica y Optometría)
Fac. de Óptica y Optometría
TRUE
pub
2023-06-17T13:27:37Z
2023-06-17T13:27:37Z
2019-06
journal article
https://hdl.handle.net/20.500.14352/13538
1523-7060
10.1021/acs.orglett.9b01465.
eng
(MAT2017-83856-C3-2-P; MAT2017-83856-C3-3-P)
IT912-16
restricted access
application/pdf
ACS (American Chemical Society)